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Synthesis 2012; 44(19): 3003-3005
DOI: 10.1055/s-0031-1290400
DOI: 10.1055/s-0031-1290400
practical synthetic procedures
A Large-Scale Synthesis of α-Olefins and α,ω-Dienes
Further Information
Publication History
Received: 01 March 2012
Accepted after revision: 08 May 2012
Publication Date:
28 June 2012 (online)
Abstract
The decarbonylation of carboxylic acids or dicarboxylic acids in the presence of a palladium catalyst above 190 °C in the absence of a solvent constitutes a mild method for the large-scale synthesis of α-olefins and α,ω-dienes.
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