Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml
Synfacts 2011(12): 1371-1371
DOI: 10.1055/s-0031-1289423
DOI: 10.1055/s-0031-1289423
Polymer-Supported Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Reduction of Nitroarenes with N2H4˙H2O Using Fe-Phen/C
R. V. Jagadeesh, G. Wienhöfer, F. A. Westerhaus, A.-E. Surkus, M.-M. Pohl, H. Junge, K. Junge, M. Beller*
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Germany
Further Information
Publication History
Publication Date:
18 November 2011 (online)
Significance
An iron-phenanthroline complex supported on carbon (Fe-phen/C) was prepared by mixing Fe(OAc)2/1,10-phenanthroline complex and vulcan XC72R carbon powder followed by pyrolysis (eq. 1). Fe-phen/C catalyzed the reduction of nitroarenes with hydrazine hydrate to give the corresponding anilines in up to 99% yield (eq. 2).