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Synfacts 2011(11): 1183-1183
DOI: 10.1055/s-0031-1289230
DOI: 10.1055/s-0031-1289230
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag
Stuttgart ˙ New York
‘Ticktock’ Cyclopolymerization
E.-H. Kang, I. S. Lee, T.-L. Choi*
Seoul National University, Korea
Further Information
Publication History
Publication Date:
19 October 2011 (online)
Significance
The authors developed and optimized the selective and ultrafast cyclopolymerization reactions of 1,6-heptadiyne derivatives using a 3rd-generation Grubbs catalyst. It is remarkable that the controlled molecular weights and the narrow PDIs were achieved for the highly dendronized polymers as well.