Pd(I)-Bridging Allyl Dimers:
A New System for the Catalytic Functionalization of Carbon Dioxide

Nilay Hazari; Damian P. Hruszkewycz; Jianguo Wu

doi:10.1055/s-0030-1260944

SYNPACTS

Pd(I)-Bridging Allyl Dimers: A New System for the Catalytic Functionalization of Carbon Dioxide

Nilay Hazari*, Damian P. Hruszkewycz, Jianguo Wu
The Department of Chemistry, Yale University, P. O. Box 208107, New Haven, CT 06520, USA
Fax: +1(203)4326144; e-Mail: nilay.hazari@yale.edu;

Abstract

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Abstract

The transition-metal-mediated functionalization of CO₂ is currently an area attracting considerable interest due to the potential benefits of utilizing CO₂ as a C₁ feedstock. Here, recent advances in CO₂ activation and functionalization using monomeric Pd η^¹-allyls are summarized. Subsequently, we discuss the chemistry of unusual Pd(I)-bridging allyl dimers, which may be masks for Pd η^¹-allyl complexes, and are stable catalysts for CO₂ functionalization.

Key words

palladium - bridging allyl complexes - carbon dioxide functionalization - homogeneous catalysis - multimetallic complexes

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