Oxidative Addition of 1,3-Dicarbonyl
Compounds to Terminal Acetylenes Mediated by Cerium(IV)
Ammonium Nitrate

Akhil Sivan; Ani Deepthi; Vidya Nandialath

doi:10.1055/s-0030-1260095

PAPER

Oxidative Addition of 1,3-Dicarbonyl Compounds to Terminal Acetylenes Mediated by Cerium(IV) Ammonium Nitrate

Akhil Sivan^a, Ani Deepthi*^a, Vidya Nandialath^b
^a Department of Chemistry, Amrita Vishwa Vidyapeetham, Kollam 690525, India
Fax: +91(476)2896178; e-Mail: anideepthi@gmail.com;
^b AstraZeneca Pvt. Ltd., Bangalore 560024, India

Abstract

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Abstract

Cerium(IV) ammonium nitrate mediated oxidative addition of 1,3-dicarbonyl compounds to terminal acetylenes to yield multisubstituted furan derivatives is reported here. The simplicity of the reaction and the ease of execution are particularly noteworthy.

Key words

cerium(IV) ammonium nitrate - oxidative addition - terminal acetylenes - multisubstituted furans - 1,3-dicarbonyl compounds

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