N-Heterocyclic Carbene Catalyzed
Hydrophosphonylation of Aldehydes

Zhi-Hua Cai; Guang-Fen Du; Lin He; Cheng-Zhi Gu; Bin Dai

doi:10.1055/s-0030-1260045

PAPER

N-Heterocyclic Carbene Catalyzed Hydrophosphonylation of Aldehydes

Zhi-Hua Cai, Guang-Fen Du, Lin He*, Cheng-Zhi Gu, Bin Dai
Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan and School of Chemistry and Chemical Engineering, Shi He Zi University, Xin Jiang 832000, P. R. of China
Fax: +86(993)2057270; e-Mail: helin@shzu.edu.cn;

Abstract

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Abstract

N-Heterocyclic carbene catalyzed Pudovik-type reaction of dimethyl trimethylsilyl phosphite and aldehydes for the construction of carbon-phosphorus bonds have been developed, providing α-hydroxyphosphonates in moderate to excellent yield.

Key words

N-heterocyclic carbene - Pudovik-type reaction - α-hydroxyphosphonates - aldehydes - C-P bond

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