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Synfacts 2010(12): 1382-1382  
DOI: 10.1055/s-0030-1258898
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart ˙ New York

Cobalt(II)-Catalyzed Stereoselective Cyclopropanation of Alkenes

Contributor(s): Hisashi Yamamoto, Patrick Brady
S. Zhu, X. Xu, J. Perman, X. P. Zhang*
University of South Florida, Tampa, USA and South China University of Technology, Guangzhou, P. R. of China
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Publikationsdatum:
22. November 2010 (online)

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Significance

The authors disclose a highly asymmetric and highly diastereoselective method of cyclopropanation of alkenes. High yields and selectivities are obtained for a wide range of ­alkenes. The products can be converted into a number of useful products, including β-amino ­acids.