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Synfacts 2010(12): 1409-1409  
DOI: 10.1055/s-0030-1258857
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Palladium-Catalyzed β-Arylation of Carboxylic Esters

Contributor(s): Paul Knochel, Andreas J. Wagner
A. Renaudat, L. Jean-Gérard, R. Jazzar, C. E. Kefalidis, E. Clot*, O. Baudoin*
Université Claude Bernard Lyon 1, Villeurbanne and Université Montpellier 2, France
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Publikationsdatum:
22. November 2010 (online)

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Significance

Functionalized chloro- and bromo­arenes smoothly arylate the β-position of carboxylic esters in the presence of lithium dicyclohexyl­amide, Pd2(dba)3, and the DavePhos ligand.