Palladium-Catalyzed β-Arylation of Carboxylic Esters

A. Renaudat; L. Jean-Gérard; R. Jazzar; C. E. Kefalidis; E. Clot; O. Baudoin

doi:10.1055/s-0030-1258857

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Synfacts 2010(12): 1409-1409
DOI: 10.1055/s-0030-1258857

Metal-Mediated Synthesis

Palladium-Catalyzed β-Arylation of Carboxylic Esters

Contributor(s): Paul Knochel, Andreas J. Wagner
A. Renaudat, L. Jean-Gérard, R. Jazzar, C. E. Kefalidis, E. Clot*, O. Baudoin*
Université Claude Bernard Lyon 1, Villeurbanne and Université Montpellier 2, France

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Publication History

Publication Date:
22 November 2010 (online)

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Significance

Functionalized chloro- and bromoarenes smoothly arylate the β-position of carboxylic esters in the presence of lithium dicyclohexylamide, Pd₂(dba)₃, and the DavePhos ligand.