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Synthesis 2011(2): 277-280
DOI: 10.1055/s-0030-1258331
DOI: 10.1055/s-0030-1258331
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New YorkSilver Nitrate Catalyzed Oxidation of Sulfides
Further Information
Received
8 October 2010
Publication Date:
15 November 2010 (online)
Publication History
Publication Date:
15 November 2010 (online)

Abstract
A variety of sulfides were converted into the corresponding sulfoxide derivatives with 70% tert-butyl hydroperoxide in water as the oxidant in the presence of catalytic quantity of silver nitrate. The method described has a wide range of application, does not involve cumbersome workup, exhibits chemoselectivity, and proceeds under mild reaction conditions, and the resulting products are obtained in good yields within a reasonable time.
Key words
oxidation - sulfide - sulfoxide - silver nitrate - tert-butyl hydroperoxide
- Supporting Information for this article is available online:
- Supporting Information
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