Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml
Synfacts 2010(7): 0817-0817
DOI: 10.1055/s-0029-1220044
DOI: 10.1055/s-0029-1220044
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Bromomagnesium Thiolate Catalyzed Tishchenko Reaction
L. Cronin, F. Manoni, C. J. O’Connor, S. J. Connon*
The University of Dublin, Ireland
Further Information
Publication History
Publication Date:
22 June 2010 (online)
Significance
A biomimetic bromomagnesium thiolate catalyzed Tishchenko-Claisen reaction was developed. Tuning of the thiolate catalyst even allows for the intermolecular coupling of aldehydes with trifluoromethylketones.