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Synthesis 2010(7): 1145-1149
DOI: 10.1055/s-0029-1219225
DOI: 10.1055/s-0029-1219225
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Oxidation of Substituted β-Diketones with Hydrogen Peroxide: Synthesis of Esters through the Formation of Bridged 1,2,4,5-Tetraoxanes
Further Information
Received
16 October 2009
Publication Date:
20 January 2010 (online)
Publication History
Publication Date:
20 January 2010 (online)

Abstract
Acid-catalyzed oxidation of alkyl- and benzyl-substituted β-diketones by hydrogen peroxide at 79-120 ˚C in a mixture of an alcohol and a strong acid (sulfuric acid, tetrafluoroboric acid, or perchloric acid) gave the corresponding esters through the formation of bridged 1,2,4,5-tetraoxanes.
Key words
esters - hydrogen peroxide - oxidations - tetraoxanes - ketones
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