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Synthesis 2009(23): 4015-4021
DOI: 10.1055/s-0029-1217029
DOI: 10.1055/s-0029-1217029
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New YorkCerium(III)-Mediated Efficient and Stereoselective Hydrochalcogenation of Terminal Alkynes
Further Information
Received
15 May 2009
Publication Date:
12 October 2009 (online)
Publication History
Publication Date:
12 October 2009 (online)
Abstract
Vinylic chalcogenides were synthesized stereospecifically by hydrochalcogenation of propargylic amines or alcohols mediated by cerium(III) chloride. The products were obtained in good yields and with high regio- and stereoselectivities.
Key words
cerium chloride - vinylic chalcogenides - hydrochalcogenation - selenium - tellurium
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One equivalent of MeOH was used for the cleavage of diphenyl diselenide.