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DOI: 10.1055/a-2720-5058
Synthesis and Investigation of Novel Nickel-based Metal Organic Frameworks
Authors
This work was partially supported by grants of the Romanian Ministry of Research, Innovation and Digitization, PNRR/2022/C9/MCID/I8, project number CF 760056/23.05.2023, code 235/29.11.2022. M.F, A.G.M. and I.M.C acknowledge the Romanian Ministry of Research, Innovation, and Digitization through the Core Program 2023-2026 (grant no. PC3-PN23080303) and project PED84/2025.
Supported by: Romanian Ministry of Research, Innovation, and Digitization PC3-PN23080303
Supported by: COST CA23139
Abstract
Metal-organic frameworks (MOFs) represent a versatile and highly tunable class of porous coordination polymers. Herein, we present the synthesis of novel MOFs using different synthetic methodologies based on a quionoxaline-multifunctional flexible ligand and nickel ions. The organic ligand was prepared via aromatic nucleophilic substitution using 2,3-dichloroquinoxaline, and its structure and purity were confirmed by NMR spectroscopy. The successful formation of the MOFs was validated by single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), and FTIR spectroscopy. The thermogravimetry revealed that these new materials are stable below 350 °C, and the analysis of the N2 adsorption–desorption isotherms confirmed the porous structure. Furthermore, the CO2 adsorption capacity at room temperature demonstrated that these materials have promising potential for carbon capture and mitigation applications.
Keywords
Metal-organic frameworks - Coordination polymer - Quinoxaline - Multifunctional ligand - Nickel ions - CO2 adsorptionPublication History
Received: 15 May 2025
Accepted after revision: 21 August 2025
Article published online:
31 October 2025
© 2025. Thieme. All rights reserved.
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