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DOI: 10.1055/a-2532-4989
Advances in the 1,2-Metalate Rearrangement Chemistry of Alkenylboronates
Welch Foundation (I-1612).
Abstract
Synthetic methods that involve the formation of multiple bonds in a one-pot fashion have played a crucial role in organic chemistry. However, many features of these approaches are still limited, such as stereocontrol and chemoselectivity, especially when nonadjacent stereocenters are formed. Herein, we outlined our efforts in addressing these challenges by advancing the 1,2-metalate shift of alkenylboronic esters.
1 Introduction
2 1,2-Migration Strategy on Nitrogen-Containing Heterocyclic Substrates
3 Enantioselective Allylation with Metal(π-Allyl) Intermediates
4 Conclusion
Publication History
Received: 19 December 2024
Accepted after revision: 04 February 2025
Accepted Manuscript online:
04 February 2025
Article published online:
21 March 2025
© 2025. Thieme. All rights reserved
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