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Synlett 2025; 36(07): 869-873
DOI: 10.1055/a-2446-3355
DOI: 10.1055/a-2446-3355
letter
Reductive Dehalogenation towards Olefins Mediated by Phase-Transfer Electrocatalysis
O.P.E., J.R.H., A.T.M., and E.R.C. would like to thank the University of Kent and the Royal Society of Chemistry for funding (E21-0257561176). J.R.H. would also like to thank the U.K.R.I. for her Future Leaders Fellowship, (MR/T020415/1).
Abstract
Mild biphasic conditions enable dibutylviologen salts to act as both phase-transfer catalysts and electrocatalysts for the electroreduction of vicinal dibromides. Optimized experimental reaction conditions permit the production of the corresponding alkenes in competitive yields for a wide range of activated and nonactivated substrates, demonstrating good functional-group tolerance.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2446-3355.
- Supporting Information
Publikationsverlauf
Eingereicht: 16. August 2024
Angenommen nach Revision: 21. Oktober 2024
Accepted Manuscript online:
21. Oktober 2024
Artikel online veröffentlicht:
04. November 2024
© 2024. Thieme. All rights reserved
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