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Synthesis 2023; 55(19): 3113-3120
DOI: 10.1055/a-2096-6841
DOI: 10.1055/a-2096-6841
paper
Synthesis of N-Phenylcarbamate by C–N Coupling Reaction without Metal Participation
The National Natural Science Foundation of China (Grant No. 21961038), and the Shanghai Cooperation Organization Science and Technology Partnership Program (No. 2022E01049).
Abstract
We have developed a new method for the synthesis of carbamates from amine and hydrazine formate. The reaction occurs in the presence of iodine and tert-butyl hydroperoxide, in which carbazates are produced via alkoxycarbonyl radical formation for cross-coupling reaction. The method exhibits broad functional group tolerance and affords a series of N-phenylcarbamates in moderate to good yields. Remarkably, our approach is metal free and utilizes cheap, readily available raw materials and relatively universal substrates.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2096-6841.
- Supporting Information
Publication History
Received: 02 April 2023
Accepted after revision: 22 May 2023
Accepted Manuscript online:
22 May 2023
Article published online:
27 June 2023
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