Migrative Thioamination of Aryne Intermediates Generated from o-Iodoaryl Triflates

Abstract

Migrative thioamination of aryne intermediates takes place using various o-iodoaryl triflates and sulfilimines. The selective migration realizes the facile synthesis of a broad range of highly functionalized o-thioaminated diaryl sulfides. We succeeded in the ring expansion of cyclic sulfilimines enabling us to prepare eight- and nine-membered organosulfurs from dibenzothiophene- and thianthrene-type sulfilimines, respectively.

Key words

arynes - sulfilimines - diaryl sulfides - thioamination - migration

Publication History

Received: 17 January 2023

Accepted after revision: 08 February 2023

Accepted Manuscript online:
08 February 2023

Article published online:
10 March 2023

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