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Synthesis 2023; 55(02): 347-353
DOI: 10.1055/a-1840-5680
DOI: 10.1055/a-1840-5680
paper
Special Issue dedicated to Prof. Alain Krief
A Selenenium-Bridged 10-Boratriptycene Lewis Acid
We acknowledge the University of Namur, the Namur Institute of Structured Matter (NISM) and the Fond National de la Recherche Scientifique (FRS-FNRS) for financial support (grant Nos.: F.4513.18 and T.0012.21 (G.B.), Fonds pour la Formation à la Recherche dans l’Industrie et dans l’Agriculture (FRIA) Ph.D. grant for A.O. (1.E.097.20), and Chargé de recherche - Fonds De La Recherche Scientifique research grant for A.C. (1.B.087.21F).
Dedicated to Prof Alain Krief for his 80th birthday.
Abstract
A non-planar triarylborane and a new member of the boratriptycene family bearing a selenium atom in bridgehead position of triptycene scaffold was generated and isolated as a boron-‘ate’ complex paired with a weakly coordinating anion. With similar electronegativity while possessing longer atom radius with respect to sulfur, the introduction a selenium atom, in the form of a selenenium moiety, at the bridgehead of a triptycene scaffold allows a very precise modification of the pyramidalization of the boron atom environment. Experimental and computational evaluation of the Lewis acidity of this new boratriptycene derivative gave qualitative information on how a modification of the pyramidalization of the boron environment affects alone Lewis acidity parameters of such pyramidal triarylborane.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1840-5680.
- Supporting Information
Publication History
Received: 21 March 2022
Accepted after revision: 02 May 2022
Accepted Manuscript online:
02 May 2022
Article published online:
09 June 2022
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For recent reviews see:
For major reviews concerning frustrated Lewis pairs see:
For miscellaneous applications see:
For recent contributions in the field of non-VSEPR main-group Lewis acids, see: