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Synthesis 2008(10): 1514-1516
DOI: 10.1055/s-2008-1072574
DOI: 10.1055/s-2008-1072574
SHORTPAPER
© Georg Thieme Verlag Stuttgart · New York
Solvent-Free Synthesis of Bis(2,2′:6′,2′′-terpyridin-4′-yl)amine and Its Metal Complexes
Weitere Informationen
Received
6 January 2008
Publikationsdatum:
07. April 2008 (online)
Publikationsverlauf
Publikationsdatum:
07. April 2008 (online)
Abstract
The key compound bis(2,2′:6′,2′′-terpyridin-4′-yl)amine was prepared in one step starting from 4′-amino-2,2′:6′,2′′-terpyridine and 4′-bromo-2,2′:6′,2′′-terpyridine in quantitative yield. In addition, we have established an easy and efficient route for the synthesis of the bromoterpyridine compound. Using the novel ligand, two ruthenium complexes were also prepared.
Key words
aminoterpyridine - bromoterpyridine - amino-bridged terpyridine - metallodendrimers
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