Synthesis of New Functionalized Cyclopentadienes To Reach Reversible Bonding between Two Substrates

Frédéric Siffer; Vincent Roucoules; Marie-France Vallat; Albert Defoin

doi:10.1055/s-2008-1032158

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Synthesis 2008(4): 515-518
DOI: 10.1055/s-2008-1032158

PAPER

Synthesis of New Functionalized Cyclopentadienes To Reach Reversible Bonding between Two Substrates

Frédéric Siffer^a, Vincent Roucoules^a, Marie-France Vallat^a, Albert Defoin*^b
^a Institut de Chimie des Surfaces et Interfaces I.C.S.I.-C.N.R.S. - UPR 9069, 15 Rue Jean Starcky, 68057 Mulhouse Cedex, France
^b Laboratoire de Chimie Organique et Bioorganique UMR 7015, ENSCMu, 3 rue Alfred Werner, 68093 Mulhouse Cedex, France
Fax: +33(3)89336875; e-Mail: Albert.Defoin@uha.fr ;

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Publication History

Received 8 August 2007
Publication Date:
31 January 2008 (online)

Abstract
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Abstract

Reversible adhesive bonding of polymer films requires new reactive chemical compounds that permit easily broken bonds between two polymer layers. This work describes the synthesis of such new molecules possessing two reactive moieties, the cyclopentadiene-terminated thiol and the cyclopentadiene-terminated amine in 50% and 70% yields, respectively, from the known, corresponding alcohol.

Key words

polymers - functional cyclopentadienes - adhesive bonding - adhesive

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