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Synfacts 2008(1): 0059-0059
DOI: 10.1055/s-2007-991430
DOI: 10.1055/s-2007-991430
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
Novel La/Trifloroacetic Anhydride Catalyzed Nucleophilic Addition
W. W. Ong, A. B. Beeler, S. Kesavan, J. S. Panek, J. A. Porco, Jr.*
Boston University, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
18. Dezember 2007 (online)
Significance
Porco’s group has developed an efficient method for addition of various carbon nucleophiles to phosphinylimines. The generation of unexpected trifluoroacetamide products indicates novel mechanistic details for the lanthanum/trifluoroacetic anhydride mediated addition reaction.