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Synthesis 2005(18): 3039-3044
DOI: 10.1055/s-2005-918411
DOI: 10.1055/s-2005-918411
PAPER
© Georg Thieme Verlag Stuttgart · New YorkPd(OAc)2/DABCO as an Inexpensive and Efficient Catalytic System for Hiyama Cross-Coupling Reactions of Aryl Halides with Aryltrimethoxysilanes
Further Information
Received
10 May 2005
Publication Date:
29 September 2005 (online)
Publication History
Publication Date:
29 September 2005 (online)
Abstract
Pd(OAc)2/DABCO was found to be an inexpensive and efficient catalyst system for Hiyama cross-coupling reactions of aryl halides with aryltrimethoxysilanes. In the presence of Pd(OAc)2, DABCO, and TBAF, coupling of a number of aryl halides with aryltrimethoxysilanes underwent efficiently to afford the corresponding cross-coupled products in moderate to excellent yields.
Key words
Pd(OAc)2 - DABCO - Hiyama cross-coupling reaction - aryl halide - aryltrimethoxysilane
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