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Synlett 2005(14): 2257-2259
DOI: 10.1055/s-2005-871964
DOI: 10.1055/s-2005-871964
LETTER
© Georg Thieme Verlag Stuttgart · New York
Synthesis of Unique Ionophores of Penta-Crown Ethers
Further Information
Received
18 April 2005
Publication Date:
12 July 2005 (online)
Publication History
Publication Date:
12 July 2005 (online)
Abstract
Structurally unique novel ionophores of penta-crown ethers were successfully synthesized. Diaza-18-crown-6 was designed as the parent crown ring. The penta-crown ethers were prepared by the reaction of 1,3,5-triacryloylhexahydro-1,3,5-triazine (TAHTA) with diaza 18-crown-6 followed by a Michael reaction. The binding interactions of the newly synthesized penta-crown ethers with alkali metal cations were examined; the results indicate that the new penta-crown ethers can bind alkali cations of different sizes.
Key words
diaza-crown ether - 1-aza-crown ether - penta-crown ether - Michael addition - ionophore
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