Synthesis of Tripodal Phenol Porphyrins: A Modular Approach to Mimic ­Enzymes with a Cross-Linked Tyrosine

Abstract

The synthesis of various tren [tris(2-aminoethyl)amine]-capped porphyrins incorporating a substituted phenol into different positions is reported. The conformations of the different ligands have been studied in ­solution by means of NMR spectroscopy.

porphyrins - spectroscopy - biomimetic synthesis - ­phenols - enzymes

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