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Synlett 2004(7): 1158-1162  
DOI: 10.1055/s-2004-825589
LETTER
© Georg Thieme Verlag Stuttgart · New York

Synthesis of Tripodal Phenol Porphyrins: A Modular Approach to Mimic ­Enzymes with a Cross-Linked Tyrosine

David Gueyrard, Amandine Didier, Christian Ruzié, Arnaud Bondon, Bernard Boitrel*
Université de Rennes1, UMR CNRS 6509, Institut de Chimie, 35042 Rennes Cedex, France
Fax: +33(2)23235637; e-Mail: Bernard.Boitrel@univ-rennes1.fr;
Further Information

Publication History

Received 11 March 2004
Publication Date:
10 May 2004 (online)

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Abstract

The synthesis of various tren [tris(2-aminoethyl)amine]-capped porphyrins incorporating a substituted phenol into different positions is reported. The conformations of the different ligands have been studied in ­solution by means of NMR spectroscopy.

Key words

porphyrins - spectroscopy - biomimetic synthesis - ­phenols - enzymes

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