New Stannyl Enamides

Sébastien Naud; Jean-Christophe Cintrat

doi:10.1055/s-2003-40213

PAPER

New Stannyl Enamides

Sébastien Naud, Jean-Christophe Cintrat
CEA/Saclay, Service de Marquage Moléculaire et Chimie Bio-organique, Bât. 547, Département de Biologie Joliot-Curie, 91191 Gif sur Yvette cedex, FRANCE
Fax: +33(1)69087991; e-Mail: jean-christophe.cintrat@cea.fr;

Abstract

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Abstract

New stannyl enamines derived from N-ethynyl oxazolidin-2-ones have been obtained. We describe for the first time the preparation of N-ethynyl oxazolidin-2-ones using trimethylsilylethynyl iodonium triflate. The first results of transmetallation and quenching experiments with prochiral carbonyl derivatives to give β-amino alcohols are also described.

Key words

enamide - hydrostannations - oxazolidinone - tin - ynamide

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References

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