O-Allylic Substitution of Hydroxylamine Derivatives Having an N-Electron-Withdrawing Substituent

Hideto Miyabe; Kazumasa Yoshida; Akira Matsumura; Masashige Yamauchi; Yoshiji Takemoto

doi:10.1055/s-2003-37526

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Synlett 2003(4): 0567-0569
DOI: 10.1055/s-2003-37526

LETTER

O-Allylic Substitution of Hydroxylamine Derivatives Having an N-Electron-Withdrawing Substituent

Hideto Miyabe^a, Kazumasa Yoshida^a, Akira Matsumura^a, Masashige Yamauchi^b, Yoshiji Takemoto*^a
^a Graduate School of Pharmaceutical Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan
Fax: +81(75)7534569; e-Mail: takemoto@pharm.kyoto-u.ac.jp;
^b Faculty of Pharmaceutical Sciences, Josai University, Keyakidai, Sakado, Saitama 350-0295, Japan

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Publication History

Received 27 January 2003
Publication Date:
26 February 2003 (online)

Abstract
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Abstract

The O-allylic substitution of hydroxylamines having an N-electron-withdrawing substituent proceeded smoothly to afford O-allylated products by using [IrCl(cod)]₂ or Pd(PPh₃)₄.

Key words

allylations - iridium - palladium - cyclizations - metathesis

References

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