Synthesis 2002(4): 0565-0569
DOI: 10.1055/s-2002-20955
PSP
© Georg Thieme Verlag Stuttgart · New York

Preparation and Reactions of Functionalized Arylmagnesium Reagents

Anne Eeg Jensen, Wolfgang Dohle, Ioannis Sapountzis, David M. Lindsay, Viet Anh Vu, Paul Knochel*
Ludwig-Maximilians-Universität München, Department Chemie, Butenandtstr. 5-13, Haus F,81377 München, Germany
e-Mail: Paul.Knochel@cup.uni-muenchen.de;
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Publikationsverlauf

Received 9 October 2001
Publikationsdatum:
28. Juli 2004 (online)

Abstract

Functionalized magnesium reagents have been prepared via an iodine-magnesium exchange. These reagents can be either trapped directly with aldehydes or transmetallated to copper or zinc to participate in cross-coupling reactions. The iodine-magnesium exchange, represent a unique method for the preparation of aryl and heteroaryl magnesium reagents.

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Sapountzis, I.; Dohle, W.; Knochel, P. Chem. Commun. 2001, 2068.