Synlett 2002(1): 0146-0148
DOI: 10.1055/s-2002-19357
LETTER
© Georg Thieme Verlag Stuttgart · New York

Palladium-Catalyzed Allylic Substitution Using in Situ Generated Allylindium Reagents

Phil Ho Lee*a, Sun-young Sunga, Kooyeon Leea, Sukbok Changba Department of Chemistry, Kangwon National University, Chunchon 200-701, Republic of Korea
Fax: +82(33)2537582; e-Mail: phlee@kangwon.ac.kr;
b Department of Chemistry, Ewha Womans University, Seoul 120-750, Republic of Korea
Further Information

Publication History

Received 10 October 2001
Publication Date:
01 February 2007 (online)

Abstract

It was found that in situ generated allylindium reagent from the reaction of allyl halides with indium is the efficient nucleophile for Pd-catalyzed allylic substitution to produce 1,5-dienes in good yield.