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Synthesis 2001; 2001(1): 0069-0074
DOI: 10.1055/s-2001-9748
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Synthesis of Stabilized Diaminophosphonium Diazaylides

Henri-Jean Cristau* , Marc Taillefer, Isabelle Jouanin
  • *Laboratoire de Chimie Organique, ENSCM, UMR 5076 du CNRS, 8 rue de l'Ecole Normale, 34296 Montpellier Cedex 5, France; Fax +33(0)4 67 14 43 19; E-mail: cristau@cit.enscm.fr and taillefe@cit.enscm.fr
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Publikationsdatum:
31. Dezember 2001 (online)

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The first examples of metalated stabilized diaminophosphonium diazaylides 7 have been synthesized in good yields from acylazides by two different synthetic pathways involving either an original and direct Staudinger reaction with the sodium phosphide (diazaylides 7′) or a more classical Staudinger reaction with diphenylphosphine and a subsequent deprotonation (diazaylides 7′). Additionally, the related new diaminophosphonium monoazaylides 6 and diaminophosphonium salts 5 have also been synthesized.

Staudinger reaction - diaminophosphonium diazaylide - diaminophosphonium monoazaylide - diaminophosphonium salt