PDF herunterladen
Synlett 2001; 2001(1): 0069-0072
DOI: 10.1055/s-2001-9715
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Enantioselective Aldol Reaction of Trimethoxysilyl Enol Ethers with Aldehydes Catalyzed by p-Tol-BINAP · AgF Complex

Akira Yanagisawa* , Yoshinari Nakatsuka, Kenichi Asakawa, Hiromi Kageyama, Hisashi Yamamoto
  • *Graduate School of Engineering, Nagoya University, CREST, Japan Science and Technology Corporation (JST) Chikusa, Nagoya 464-8603, Japan; Fax +81-52-789-3222; E-mail: yamamoto@cc.nagoya-u.ac.jp
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
31. Dezember 2001 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

New catalytic asymmetric Mukaiyama-type aldol reaction using trimethoxysilyl enol ethers was achieved using p-Tol-BINAP · AgF complex as a catalyst. High syn- and enantioselectivities were obtained both from the E- and Z-silyl enol ethers.

enantioselective aldol reaction - silyl enol ethers - aldehydes - BINAP · silver(I) complex - asymmetric catalysis

      >