Synlett 2001; 2001(12): 1875-1877
DOI: 10.1055/s-2001-18753
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Living Ring-Opening Metathesis Polymerization of Enantiopure Norbornene-type β-Amino Acid Derivatives

Carsten Bolm* , Christian L. Dinter, Ingo Schiffers, Laurent Defrère
  • *Institut für Organische Chemie der RWTH Aachen, Professor-Pirlet-Str. 1, 52056 Aachen, Germany; Fax: + 49(241)8092391; E-mail: Carsten.Bolm@oc.RWTH-Aachen.de
Further Information

Publication History

Publication Date:
04 December 2001 (online)

The ring-opening metathesis polymerization of enantiopure norbornene-type monomers using Grubbs’ ruthenium carbene initiator gives access to a new class of poly-β-amino acid derivatives. Kinetic investigations and molecular weight determinations proved the living nature of the polymerization allowing control over chain length and polymer weight.

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