Download PDF
Synlett 2001; 2001(Special Issue): 1055-1064
DOI: 10.1055/s-2001-14625
new tools in synthesis
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Recent Advances of BINAP Chemistry in the Industrial Aspects

Hidenori Kumobayashi* , Takashi Miura, Noboru Sayo, Takao Saito, Xiaoyong Zhang
  • *Central Research Laboratory, Takasago International Corporation, 1-4-11 Nishi-yawata, Hiratsuka, Kanagawa 254-0073, Japan; Fax (0463)25-2084; E-mail: TIC00544@nifty.com
Further Information

Publication History

Publication Date:
31 December 2001 (online)

  PDF Download Permissions and Reprints All articles of this category

New efficient synthetic methods of optically active BINAP [BINAP = 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl] and its variants are described. Application of these BINAP variants in asymmetric catalytic hydrogenation of prochiral ketones and olefins to various industrially important compounds is discussed.

BINAP ligands - ruthenium and iridium catalysts - asymmetric hydrogenation - ketones - unsaturated carboxylic acids

      >