Synthesis 2001(7): 1081-1085
DOI: 10.1055/s-2001-14565
PAPER
© Georg Thieme Verlag Stuttgart · New York

A New Synthesis of Triarylbismuthanes via Directed Ligand Coupling of Oxazoline-Substituted Tetraarylbismuthonium Salts: Synthesis of Polystyrenes Bearing the Diarylbismuthino Group

Yoshihiro Matano*, Shameem Ara Begum1a, Hitomi Suzuki1b
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan
Fax: +81(75)7534000; e-Mail: matano@kuchem.kyoto-u.ac.jp;
Further Information

Publication History

Received 15 February 2001
Publication Date:
30 September 2004 (online)

Abstract

Triarylbismuthanes bearing a vinyl, formyl, or acetyl group have been prepared in good yield via the directed ligand coupling of oxazoline-substituted tetraarylbismuthonium salts. Radical polymerization of the resulting diaryl(4-vinylphenyl)bismuthanes produced bismuth-containing polystyrenes soluble in organic solvents.

    References

  • 1a

    Current address: Department of Chemistry, Faculty of Physical Sciences, Shahjalal University of Science and Technology, Sylhet, Bangladesh.

  • 1b

    Current address: Department of Chemistry, School of Science, Kwansei Gakuin University, Uegahara, Nishinomiya 662-8501, Japan

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