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Synlett 2001; 2001(5): 0621-0622
DOI: 10.1055/s-2001-13362
DOI: 10.1055/s-2001-13362
letter
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Novel Synthesis of Cyclic α-Amino Acid Esters via Ene Reaction and Ruthenium-catalyzed Ring Rearrangement
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Publication History
Publication Date:
31 December 2001 (online)
New fluorinated unsaturated cyclic α-amino acid esters were obtained by ene reaction of methylenecycloalkanes with electrophilic imines (CF3)(MeO2C)C=N-PG, followed by ruthenium-catalyzed ring rearrangement involving mixed ROM-RCM metathesis.
fluorinated amino acids - cyclic amino esters - ene reaction - ROM-RCM metathesis