Synlett 2001; 2001(5): 0621-0622
DOI: 10.1055/s-2001-13362
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Novel Synthesis of Cyclic α-Amino Acid Esters via Ene Reaction and Ruthenium-catalyzed Ring Rearrangement

Sergey N. Osipov* , Natalia M. Kobelíkova, Gregory T. Shchetnikov, Alexey F. Kolomiets, Christian Bruneau, Pierre H. Dixneuf
  • *A. N. Nesmeyanov Institute of Organoelement Compounds, Vavilov st. 28, 117813 Moscow, GSP-1, Russia; Fax + 7 095 135 5085; E-mail: osipov@ineos.ac.ru
Further Information

Publication History

Publication Date:
31 December 2001 (online)

New fluorinated unsaturated cyclic α-amino acid esters were obtained by ene reaction of methylenecycloalkanes with electrophilic imines (CF3)(MeO2C)C=N-PG, followed by ruthenium-catalyzed ring rearrangement involving mixed ROM-RCM metathesis.

    >