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Synlett 2001; 2001(3): 0385-0387
DOI: 10.1055/s-2001-11414
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Asymmetric Allylic Amination Catalyzed by Pd-BINAP Complexes

Hidehiko Kodama* , Toshiji Taiji, Tetsuo Ohta, Isao Furukawa
  • *Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0394, Japan; Fax + 81-7 74-67 89; E-mail: tota@mail.doshisha.ac.jp
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Publikationsdatum:
31. Dezember 2001 (online)

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The asymmetric allylic amination of rac-1,3-diphenyl-2-propenyl acetate (1) with potassium phthalimide (2 b) has been carried out in the presence of 2.5 mol% Pd2(dba)3 · CHCl3 and 5.0 mol% (S)-Tol-BINAP to give the allylic product (3 b) in 75% yield with 99% ee.

asymmetric catalysis - aminations - palladium - phosphorus - allyl complexes