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Synlett 2001; 2001(2): 0275-0277
DOI: 10.1055/s-2001-10770
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Stereoselective Synthesis of 1,2,5,6-Tetrahydro 1,3-Oxaza-4-phospha-2-phosphorine 2-Oxides through Reaction of P-Diphenyl(alkyl) (N-diphenylphosphoryl)phosphazenes with Aldehydes and Ketones

Emma Peralta Pérez* , Birte Ahrens, Matthew G. Davidson, Paul R. Raithby, Simon J. Teat, Isidro Pérez Álvarez, Fernando López Ortiz
  • *Área de Química Orgánica, Universidad de Almería, Carretera de Sacramento s/n, 04120 Almería, Spain; Fax +34 950015481; E-mail: flortiz§ual.es
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Publication Date:
31 December 2001 (online)

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Novel 1,2,5,6-tetrahydro 1,3-oxaza-4-phospha-2-phosphorine 2-oxides have been synthesised stereoselectively through addition of aldehydes and ketones to lithiated (N-diphenylphosphoryl)phosphazenes.

phosphazenes - stereoselective synthesis - carbanions - phosphorus heterocycles - X-ray structure

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