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Synlett 2000; 2000(2): 233-235
DOI: 10.1055/s-2000-6506
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Diels-Alder Reaction of Ni(II) β-Vinyl-meso-tetraphenylporphyrin; A General Method for Synthesis of Functionalized Porphyrins

Kiyoshi Matsumoto* , Shinya Kimura, Takuya Morishita, Yukihiro Misumi, Naoto Hayashi
  • *Graduate School of Human and Environmental Studies, Kyoto University, Kyoto 606-8501, Japan; Fax +81-75-7 53-29 69; E-mail: kio@highpr.jinkan.kyoto-u.ac.jp
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Publication Date:
31 December 2000 (online)

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Ni(II)β-Vinyl-meso-tetraphenylporphyrin underwent Diels-Alder reaction with a variety of dienophiles to give the corresponding porphyrins via 1,3-hydrogen shift of the initial adducts in good to moderate yields.

Diels-Alder Reaction - porphyrin - 1,3-sigmatropy - high pressure