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Synthesis 2000; 2000(2): 251-254
DOI: 10.1055/s-2000-6247
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A Combination of Allyltitanation and Tandem Aldol-Tischtschenko Reactions Using Tetraisopropoxytitanium

Christophe Delas* , Claude Moïse
  • *Laboratoire de Synthèse et d'Electrosynthèse Organométalliques (UMR 5632), Faculté des Sciences, 6 bd Gabriel, F-21000 Dijon, France; Fax +33 (3) 80 39 60 76; E-mail: claude.moise@u-bourgogne.fr
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Publication Date:
31 December 2000 (online)

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An allyltitanation reaction coupled with a tandem aldol-Tischtschenko reaction catalyzed by tetraisopropoxytitanium allows the access to stereocontrolled polypropionate systems in two steps.

allyl complexes - titanium - aldol reactions - Tischtschenko reaction - polypropionates - tandem reactions

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