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Synlett 1999; 1999(S1): 877-880
DOI: 10.1055/s-1999-3096
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Conversion of Ascomycin into its Furano-Isomers

Karl Baumann* , Berndt Oberhauser, Gertrude Strnadt, Hermann Knapp, Gerhard Schulz, Maximilian A. Grassberger
  • *Department of Chemistry and Pharmacology, Novartis Forschungsinstitut, Brunner Strasse 59, A-1235 Vienna, Austria; Fax +43(1)86 63 43 54; E-mail: karl.baumann@pharma.novartis.com
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Publication Date:
31 December 1999 (online)

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The high reactivity of the unmasked tricarbonyl segment of ascomycin potentially allows the formation of numerous isomers in the binding domain. In this paper, the synthesis of a novel class of hypothetical equilibrium products of ascomycin is described.

ascomycin - isomers - binding domain - tricarbonyl

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