Download PDF
Synlett 1999; 1999(9): 1415-1416
DOI: 10.1055/s-1999-2874
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Reduction of Organic Halides with Tri-2-Furanylgermane: Stoichiometric and Catalytic Reaction

Tomoaki Nakamura* , Hideki Yorimitsu, Hiroshi Shinokubo, Koichiro Oshima
  • *Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Yoshida, Kyoto 606-8501, Japan; Fax +81-75-761-88 46; E-mail: oshima@fm1.kuic.kyoto-u.ac.jp
Further Information

Publication History

Publication Date:
31 December 1999 (online)

  PDF Download  Permissions and Reprints All articles of this category

Triethylborane-induced radical reduction of organic halides with tri-2-furanylgermane provided the corrresponding reduced compounds in good yields. Radical cyclization of β-haloalkyl allyl ether or 6-halo-1-alkene afforded five-membered products under the same reaction conditions. These reactions proceeded with NaBH4 in the presence of a catalytic amount of germanium hydride.

tri-2-furanylgermane - triethylborane - reduction - radical reaction

      >