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Synlett 1999; 1999(6): 692-694
DOI: 10.1055/s-1999-2743
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Synthetic Study of Pinnatoxin A: Intramolecular Diels-Alder Approach to the AG-ring

Akihiro Ishiwata* , Satoshi Sakamoto, Takeshi Noda, Masahiro Hirama
  • *Department of Chemistry, Graduate School of Science, Tohoku University, and CREST, Japan Science and Technology Corporation (JST), Sendai 980-8578, Japan; Fax +81 (22) 2 17-65 66; E-mail: hirama@ykbsc.chem.tohoku.ac.jp
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Publication Date:
31 December 1999 (online)

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A chiral quaternary carbon (C5) with the G-ring of pinnatoxin A has been diastereoselectively constructed via an intramolecular Diels-Alder reaction.

pinnatoxin A - diastereoselectivity - Ca2+ channel - intramolecular Diels-Alder reaction - convergent synthesis

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