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Synlett 1999; 1999(5): 569-570
DOI: 10.1055/s-1999-2698
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A Convenient and Stereoselective Synthesis of (E)-Vinylseleno Zirconocenes and (E)-Vinylic Selenol Esters

Xian Huang* , Jun-Hua Wang
  • *Department of Chemistry, Zhejiang University (Campus Xixi), Hangzhou, 310028, P. R. China; Fax and telephone: (+86)05 71-8 80 70 77 ; E-mail: huangx.@public.hz.zj.cn
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Publication Date:
31 December 1999 (online)

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The insertion of elemental selenium into the Csp2-Zr bond of alkenylchlorozirconocenes affords (E)-vinylseleno zirconocenes, which were trapped by acyl chlorides giving (E)-vinylic selenol esters in good yields.

hydrozirconation - vinylseleno zirconocenes - vinylic selenol esters

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