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Synlett 1999; 1999(5): 611-613
DOI: 10.1055/s-1999-2683
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Regioselective Alkylation of 1-Alkoxy-3-phenylseleno-1-alkenes

Yutaka Nishiyama* , Yoshihiro Kishimoto, Kazuyoshi Itoh, Noboru Sonoda
  • *Department of Applied Chemistry, Faculty of Engineering & High Technology Research Center, Kansai University, Suita, Osaka 564-0874, Japan; Fax +81-6-63 39-40 26; E-mail: nishiya@ipcku.kansai-u.ac.jp
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Publication Date:
31 December 1999 (online)

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The addition of various electrophiles to phenylseleno-substituted allyllithium, which was generated in situ by the reaction of 1-alkoxy-3-phenylseleno-1-alkene with LDA, gave the corresponding α-addition products in moderate to good yields with high regioselectivity.

regioselective - alkylation - 1-alkoxy-3-phenylseleno-1-alkenes - LDA - alkyl halides

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