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Synlett 1999; 1999(5): 581-583
DOI: 10.1055/s-1999-2657
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Novel Three Component Coupling of Ketone, Cyclic Ether and Epoxide using Aluminum Tris(2,6-diphenylphenoxide) (ATPH)

Susumu Saito* , Satoko Yamazaki, Masahito Shiozawa, Hisashi Yamamoto
  • *Graduate School of Engineering, Nagoya University, CREST, Japan Science and Technology Corporation (JST), Furo-Cho, Chikusa, Nagoya 464-8603, Japan; Fax +81(52)7 89 32 22; E-mail: j45988@nucc.cc.nagoya-u.ae.jp
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Publikationsdatum:
31. Dezember 1999 (online)

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A ketone, cyclic ether, and epoxide are combined in one-pot using aluminum tris(2,6-diphenylphenoxide) (ATPH) and LDA, the latter agent being applied as the trigger for the reaction.

three component coupling - ATPH - enolate - cyclic ether - epoxide