Download PDF
Synlett 1999; 1999(3): 327-329
DOI: 10.1055/s-1999-2614
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Cross-Coupling of Organostannanes with Organic Iodides Catalyzed by Silica-Supported Poly[3-(2-cyanoethylsulfanyl)propylsiloxane palladium] Complex Under Aqueous Medium

Suk-Ku Kang* , Tae-Gon Baik, Si-Young Song
  • *Department of Chemistry and Research Institute for Basic Sciences, Sungkyunkwan University, Natural Science Campus, Suwon 440-746, Korea; Fax +82 (3 31) 2 90 70 79; E-mail: skkang@chem.skku.ac.kr
Further Information

Publication History

Publication Date:
31 December 1999 (online)

  PDF Download  Permissions and Reprints All articles of this category

The cross-coupling of organostannanes with organic iodides was achieved in the presence of a catalytic amount of a silica-supported sulfur palladium complex (5 mol %) in CH3CN/H2O (4 : 1) at 80 °C for 5 h in 71-89% yields.

silica-supported palladium - cross-coupling - organostannanes - Stille coupling - aqueous medium

      >