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Synlett 1998; 1998(10): 1093-1095
DOI: 10.1055/s-1998-1867
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Diastereoselective Anomeric Oxygen to Carbon Rearrangements of Silyl Enol Ether Derivatives of Lactols

Darren J. Dixon* , Steven V. Ley, Edward W. Tate
  • *Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, U.K.
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Publication Date:
31 December 2000 (online)

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Lewis acid promoted oxygen to carbon rearrangement of anomerically linked silyl enol ethers gives a new and diastereoselective route to the corresponding 2-α-hydroxyketone substituted products.

diastereoselective - anomeric rearrangement - silyl enol ether