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Synlett 1998; 1998(2): 192-194
DOI: 10.1055/s-1998-1598
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A Novel Transition Metal-Catalyzed Route to Functionalized Dihydropyrans and Tetrahydrooxepines

Floris P. J. T. Rutjes* , T. Martijn Kooistra, Henk Hiemstra, Hans E. Schoemaker
  • *Laboratory of Organic Chemistry, Amsterdam Institute of Molecular Studies, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The Netherlands; Fax +31 20 525 56 70; E-mail: florisr@org.chem.uva.nl
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Publication Date:
31 December 2000 (online)

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A straightforward route for the synthesis of α,α'-disubstituted dihydropyrans and tetrahydrooxepines has been developed involving Pd- and Ru-catalyzed reactions.

2,6-dihydropyrans - ring-closing metathesis - Pd-catalysis - methoxy-allene - oxycarbenium ion

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