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Effects of Subjoin Lewis Acid on the Catalytic Asymmetric Allylic Transfer Reactions of Aldehydes Promoted by BINOL-Ti(IV) Complex
31 December 2000 (online)
Practical and efficient catalytic asymmetric allylic transfer reactions of achiral aldehydes with tin reagents promoted by BINOL-Ti(IV) complex are achieved with high enantioselectivity by the utilization of subjoined Lewis acid, B(OMe)3.
chiral Lewis acid - catalytic process - BINOL-Ti(IV) complex - asymmetric allylation - asymmetric propargylation