Subscribe to RSS
Synthetic Usefulness of the Cobalt(I)-Mediated Ene Type Reaction for the Diastereoselective Construction of Bicyclo[n.3.0]derivatives
31 December 2000 (online)
Cobalt(I)-catalyzed cycloisomerization of cyclic ℇ-acetylenic β-ketoesters 1 led to bicyclo[n.3.0]derivatives 2 in high yield and with a total stereocontrol of two contiguous centers.
ene type reaction - cobalt(I) - diastereoselectivity - cycloisomerization - bicyclo[n.3.0]derivatives