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Synlett 1997; 1997(8): 913-914
DOI: 10.1055/s-1997-932
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Activation of 2-Alkyn-1-ols by [Fe(C5Me5)(CO)2]+: New Route to α,β-Unsaturated Acyl Complexes

Géraldine Poignant, Françoise Martin, Véronique Guerchais*
  • *UMR 6509 CNRS-Université de Rennes 1, Organométalliques et Catalyse: Chimie et Electrochimie Moléculaires, Beaulieu, 35042 Rennes, France, Fax 33 (0)2.99.28.16.46; E-mail guerchai@univ-rennes1.fr
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Publication Date:
31 December 2000 (online)

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Activation of propargyl alcohol derivatives by [Fe(C5Me5)(CO)2]+ opens a new route to α,β-unsaturated acyl complexes [Fe(C5Me5)(CO)2{C(O)CH=CR1R2}], precursors of the corresponding (alkenyl)carbene complexes.

iron - propargyl alcohols - 2-alkenoyl - unsaturated carbene complexes

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