Synlett 1997; 1997(8): 913-914
DOI: 10.1055/s-1997-932
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Activation of 2-Alkyn-1-ols by [Fe(C5Me5)(CO)2]+: New Route to α,β-Unsaturated Acyl Complexes

Géraldine Poignant, Françoise Martin, Véronique Guerchais*
  • *UMR 6509 CNRS-Université de Rennes 1, Organométalliques et Catalyse: Chimie et Electrochimie Moléculaires, Beaulieu, 35042 Rennes, France, Fax 33 (0); E-mail [email protected]
Further Information

Publication History

Publication Date:
31 December 2000 (online)

Activation of propargyl alcohol derivatives by [Fe(C5Me5)(CO)2]+ opens a new route to α,β-unsaturated acyl complexes [Fe(C5Me5)(CO)2{C(O)CH=CR1R2}], precursors of the corresponding (alkenyl)carbene complexes.